Based on those screenshots, it looks like Relayed Transfers is enabled, but not because of Hotspots, Eye-Fi View or online sharing for Photos/RAW. If you have online sharing turned on for Videos, turn that off, then see if you can turn off Relayed Transfers. Add your wi-fi network to the card again and see if this helps. You could also enable photo and video uploads to the Mac in case some deliveries are stuck.
If those don't help, we should check your Eye-Fi card log and Eye-Fi Helper log, so we can determine where the delays are occurring.
Please shoot a couple new photos, wait a few minutes for some upload activity, then locate the logs and attach them to an email to firstname.lastname@example.org
To retrieve the card log: connect the card to your Mac, click the Eye-Fi Helper icon in your Apple menu bar, and choose "Get Eye-Fi Card log". Save the log somewhere convenient, then attach it to your new email.
The Eye-Fi Helper log is found in /Users/<your username>/Library/Eye-Fi as "EyeFi.log" (the ".log" may be hidden depending on your system). Please quit Eye-Fi Center and Helper, then attach this log file to the same email. To view your Library folder, click the Finder's Go menu while holding your Option/Alt key, as described here:http://www.tuaw.com/2011/08/25/mac-101- ... r-in-lion/
Send us those logs and we'll take a look.